2018年11月30日星期五

Advantages of Carbon Steel


Efficiently Malleable
Among the most helpful attributes of light steel is it could be bent, twisted and cut to make the desired shape simpler than other alloy. It is one of the reasons why Carbon Steel Bend is popular in many industries for structural applications. The high degree of demand makes light steel a broadly produced material and so an extremely reasonably priced material.
Weight
In comparison to high carbon steel light carbon steel is milder. The ratio of carbon is the key influencing element for the weightreduction. Dealing with light steel is, thus, easier and can be used for manufacturing automobile parts, pipelines and i.e. fences and decorations for houses and businesses.
Greatly Reasonably Priced
Whilst working on a very low budget, Carbon Steel Bend China turns out to be the ideal. While light steel is comparatively more affordable than other metals you'll need to contemplate that you might need to take care of it to stop it from rust.
Carbon Steel Bend

2018年11月29日星期四

Underwater ultrasonic nondestructive testing technology


Why study underwater ultrasonic testing
Along with the development of modern industry and science and technology, nondestructive testing technology in equipment and equipment operation, the guarantee of product quality, increase productivity, reduce costs, and other fields play a greater role, nondestructive testing has already developed into is an independent comprehensive discipline, and ultrasonic testing technology in nondestructive testing field occupies an extremely important position, have got extensive application in many fields.
However, the modern petroleum industry has gradually developed to the sea, and there is an increasing demand for underwater ultrasonic inspection technology. Therefore, underwater ultrasonic inspection technology is favored by various offshore oil companies.  
Underwater ultrasonic testing (UWUT) is one of the most important underwater nondestructive testing methods.
The underwater installation or repair of Marine engineering structures requires a lot of underwater welding, and the quality of the weld is often much worse than that of the land.
UWUT must be used to detect the quality of the weld. During the operation of platform, submarine pipeline and other structural parts, it is necessary to conduct UWUT as well as to master the expansion of internal defects.
【Ultrasonic testing has the following advantages】
1. It is applicable to nondestructive testing of metal, non-metal and composite materials and other components;
2. With strong penetration ability, the internal defects of specimens within a large thickness range can be detected. For gold materials, thin wall pipe and plate with thickness of 1~2mm can be tested, and steel forgings with length of several meters can also be tested.
3. Relatively accurate defect positioning;
4. High detection rate of area type defects;
5. High sensitivity, which can detect defects with small internal dimensions of the specimen;
6. Low cost, fast speed, portable equipment, harmless to human body and environment, and convenient for on-site use.
As China's oil industry gradually moves into the sea, the importance of underwater technology becomes increasingly prominent. Regular inspection is required for underwater pipelines, underwater operating machinery and equipment, etc., which rely heavily on underwater ultrasonic inspection technology. The development of underwater ultrasonic inspection technology will directly affect the development of the Marine industry in the future.
Therefore, it is very necessary to study underwater ultrasonic testing technology.
02
Development status of ultrasonic nondestructive testing in China
In recent years, China has made great progress and development in ultrasonic nondestructive testing. Ultrasonic nondestructive testing (NDT) has been applied to almost all industrial sectors and is increasingly being used.
The basic research on the theory, method and application of ultrasonic testing technology is deepening gradually, and many advanced international achievements have been achieved. Many different applications of microcomputer control automatic ultrasonic testing system have been applied in practical production.
The main research of our country in this respect is: computerized ultrasonic equipment; User friendly interface operating system software; Ultrasonic digital signal processing, including artificial intelligence, neural network, pattern recognition, phase compensation, etc. High frequency ultrasonic nondestructive testing technology: various scanning imaging technology; Multi-coordinate, multi-channel automatic ultrasonic detection system; Ultrasonic robot detection system: automatic scanning ultrasonic imaging detection of complex components (such as the development and research of auxiliary equipment such as multi-dimensional probe adjustment structure with over 5 dimensions).
Many of these achievements have reached the international advanced level, and these researches are the guarantee for the continuous development of ultrasonic nondestructive testing technology in China.
However, China's ultrasonic nondestructive testing industry from the overall level, and developed countries have a large gap in quality inspection. Specific performance in the following aspects:
1. The proportion of senior technical staff and senior operation staff in the inspection professional team is small, which greatly hinders the progress of automation, intelligence and imaging of ultrasonic nondestructive testing technology.
The older generation of experienced flaw detection workers lack the theoretical summary of translating practical experience into theoretical summary, while the younger inspection workers have rich computer and other modern technology but lack practical experience. This may lead to the existing ultrasonic testing software system to varying degrees of defects and reduce the reliability of testing.
Especially like expert system software, to and automatically judge injuries. The writing of software that automatically evaluates the level of defects should be given enough attention.
To organize certain manpower and talent to collect and summarize the field experience of ultrasonic nondestructive testing, constantly enrich the testing theory and standard, and combine the non-destructive testing technical staff and computer technical staff, so as to develop practical nondestructive testing software.
In addition, a correct concept should be set up for all kinds of non-destructive testing software. Any software relies on correct detection methods, testing status and results obtained within certain applicable limits.
2. Relatively few professional non-destructive testing staff and low utilization rate of existing non-destructive testing equipment. After 40 years of development, China's nondestructive testing technology has been applied in nearly 30 system fields, and nearly 300,000 people are directly engaged in non-destructive testing technology.
According to the investigation and survey of large machinery manufacturing enterprises in China, they all have many non-destructive testing equipment. However, due to the lack of understanding of the importance of non-destructive testing and the lack of staff specialized in non-destructive testing, non-destructive testing has not played its due role in production.
The lack of books on nondestructive testing is not conducive to the training of non-destructive testing successors.
3. Lack of attention to the application of information technology in the field of nondestructive testing technology. When information technology is combined with NDT, a large amount of information can be obtained from the detection process to the maximum extent. The construction of nondestructive testing information technology in China is still in a rather weak stage.

In a word, the problems that need to be solved urgently at present are those related to and to be solved in practical engineering application, such as the standardization of detection methods, the standardization of defect detection, the formulation of testing and acceptance standards, the procedural operation procedures, and the informatization of detection technology.
In addition, attention should be paid to the national unified training, appraisal and assessment of NDT qualification, so as to make the training of NDT personnel in line with international standards.
03
Principle of underwater ultrasonic testing technology
The UWUT is not simply moving the uut method from the ground to the complex underwater environment. Some seemingly simple problems on land must be properly addressed in the UWUT. For example, the selection, testing, adjustment and sensitivity setting of probe instrument, how to observe, record and judge underwater, etc.
The basic principle of UWUT is the same as that of conventional UT method on land. Pulse reflection method and resonance method are the main methods. When this method is used for detection, it is necessary to establish contact between divers and onshore technicians from the perspective of ultrasonic echo display, so as to help UWUT workers to make correct judgment. Therefore, UWUT usually adopts land and water synchronous ultrasonic detection system.
【Underwater ultrasonic testing instrument and probe】
Like all UWNDT devices, UWUT devices must meet the requirements of relevant specifications and standards (such as asme73-wa/oct-18, BS4994, etc.). Usually the instrument manufacturer or owner shall be approved by the relevant classification society or by a single instrument/device.
(1) water tightness and water pressure resistance, especially the main control display immersed in the water, are like a pressure vessel, whose pressure-resistant shell and polypropylene window should be able to withstand the external pressure at a depth of tens of meters to prevent the working depth from being crushed and destroyed, and to withstand the internal overpressure in the water environment.
(2) the staff shall ensure that all submersible equipment and devices are safe, so that the diver shall avoid electric shock as much as possible; Generally speaking, the fault current passing through the diver's body shall not exceed the "sensitivity" of 0.5mA (ac) or 2mA (dc).
(3) technical performance usually, the underwater ultrasonic instrument must be able to apply pulse reflection technology and double probe technology, covering a minimum frequency range of 2-6mhz. Under test conditions, the echo of 5% of the total amplitude of the screen can be clearly detected. At the same time, can be seen from the front directly depict the benchmark curve flat screen, apply to the longitudinal wave sensors, sensor T/R, 45 °, 60 °, 70 ° and 80 ° Angle probe.
(4) the environmental adaptability system and components must adapt to its working environment.
(5) operability bar is usually designed to be less buttons and easy to identify, easy to operate and calibrate. Each UWUT device should have a corresponding operation manual (including equipment/instrument, application limits, and specification of design criteria that affect the application of the equipment) and calibration procedures. The DAC100% curve positioning reference sensitivity was obtained by adjusting the maximum echo of 1.6 mx1 and 6mmX38mm square groove reflection in the APIRPZXA test block. The sensitivity compensation is usually determined by considering materials, curvature, coupling and other factors, generally 12dB.
(6) before and after each inspection, the incident point, refractive index Angle and DAC curve of the probe must be checked.
(7) coupling agent underwater detection, seawater is a natural coupling agent. Therefore, all adjustment and testing on land shall adopt seawater coupling.
In conclusion, it can be concluded that NDT technology has a wide range of applications under water and can play a very important role under water, especially for the detection of such close instruments as water pressure vessels.

2018年11月28日星期三

Stainless steel pickling passivation process control


1.Pretreatment of pickling passivation
Stainless steel workpiece before pickling passivation, if there are surface dirt, should be through mechanical cleaning, and then oil degreasing.If the acid lotion and passivation solution cannot remove grease, oil surface will affect the quality of the pickling passivation, therefore oil removal cannot omit, lye, emulsifier, organic solvent and steam can be used, etc。
2.Control of CL- in acid lotion and washing water
Some stainless steel acid lotion or pickling paste with hydrochloric acid, perchloric acid,Ferric chloride and sodium chloride, chlorine ion corrosion medium as the main agent or agents to remove surface oxide layer, in addition to the grease with chlorinated organic solvent such as trichloroethylene, thereby preventing stress corrosion cracking is not appropriate。In addition, industrial water can be used for preliminary washing water, but halogen content should be strictly controlled for final cleaning water. Deionized water is usually used. Such as petrochemical austenitic stainless steel pressure vessel for hydrostatic test water, control the content of C1 - no more than 25 mg/L, if cannot meet the requirements, can be added to sodium nitrate in water treatment, make it meet the requirements, C1 - levels, can destroy the passive film of stainless steel, is pitting, crevice corrosion, stress corrosion cracking.
3.Process control of pickling passivation
Nitrate solution separately used to remove free iron and other metal contamination is effective, but to remove oxide, thick corrosion products, tempering membrane is invalid, such as general HNO3 + HF solution should be adopted, in order to convenient and safe in operation and fluoride can substitute for HF。HNO3 solution alone does not contain corrosion inhibitor, but when HNO3+HF acid is washed, Lan-826 is required. Use HNO3+HF pickling to keep the concentration at a ratio of 5:1 to prevent corrosion. High temperature should be lower than 49 ℃, such as, HF will evaporate.
Of passivation solution, HNO3 should be controlled between 20% - 50%, according to the electrochemical tests, HNO3 concentration less than 20% treatment of passivation film quality is not stable, easy to produce pitting, but also should not be greater than 50% HNO3 concentration, to prevent passivation.The one-step process of deoiled pickling passivation and passivation was adopted. Although the operation was simple and the working hours were saved, there would be corrosive HF in the pickling passivation solution (paste), so the final protective film quality was not as good as that of the multi-step method.
During pickling, the concentration, temperature and contact time of acid can be adjusted within a certain range. As the growth of the acid wash time, must pay attention to the change of the acid concentration and metal ion concentration, attention should be paid to avoid acid, titanium ion concentration should be less than 2%, otherwise it will lead to serious pitting. Generally speaking, increasing the pickling temperature will accelerate and improve the cleaning effect, but may also increase the risk of surface contamination or damage.
4.Control of pickling under stainless steel sensitization
Some stainless steel due to poor heat treatment or welding cause sensitization, using HNO3 + HF acid may produce intercrystalline corrosion, caused by the intergranular corrosion cracks at runtime, or cleaning, or in the subsequent processing, can enrichment halide, caused by stress corrosion. These sensitized stainless steels are generally not suitable for scaling or pickling with HNO3+HF solution. If this pickling is necessary after welding, use ultra-low carbon or stabilized stainless stee.
5.Acid cleaning of stainless steel and carbon steel components
For stainless steel and carbon steel (such as composite stainless steel tube and tube plate in heat exchanger with carbon steel shell), pickling passivation if using HNO3 or the serious corrosion of carbon steel, HNO3 + HF should then add appropriate corrosion inhibitors such as Lan - 826.
When the stainless steel and carbon steel assembly in the sensitized status, cannot use HNO3 + HF acid, glycolic acid can be used (2%) + formic acid (2%), corrosion inhibitor, temperature 93 ℃, time of 6 h + corrosion inhibitor or EDTA ammonium neutral solution, temperature: 121 ℃, time: 6 h, then wash with hot water and soaked 10 mg/L ammonium hydroxide + 100 mg/L of hydrazine
6.Post-treatment of pickling passivation
Stainless steel workpiece after pickling and flushing water, available containing 10% (mass fraction) NaOH + 4% (mass fraction) of KMnO4 alkali 1 raw potassium permanganate solution soak 5 in 71 ~ 82 ℃ ~ 60 min, to remove acid residue, and then rinse thoroughly with water, and dry。After the surface of stainless steel is acid-washed and passivated, there are flower spots or stain spots, which can be cleaned by fresh passivating liquid or high concentration nitric acid. Stainless steel equipment or components with final acid pickling passivation shall be protected by polyethylene film covering or wrapping to avoid contact between different metals and non-metals.
The treatment of acid and passivated effluent should comply with the national regulations on environmental protection. For example, fluorinated wastewater can be treated with lime milk or calcium chloride. As far as possible, the passivation solution does not use dichromate. If there is chromium containing wastewater, ferrous sulfate can be added for reduction treatment.
Pickling may cause martensitic stainless steel hydrogen embrittlement, such as the need to go through heat treatment of oxygen (heated to 200 ℃ heat preservation for a period of time).
The quality inspection
7.Quality inspection of stainless steel pickling passivation
The passivation film of the product is usually inspected on the sample because chemical inspection will destroy it. Examples of methods are as follows:
(1)titration test of copper sulfate
8g CuS04+500mL H20+2 ~ 3mLH2SO4 solution was used to drip into the surface of the sample to keep it wet. If no copper was precipitated within 6min, it was qualified.
(2)titration test of potassium cyanide of high iron
2mL HCl+1mL H2SO4+1g K3Fe(CN)6+97mL H20 solution was dropped on the surface of the sample, and the quality of the passivated film was determined by the number of blue spots generated and the length of time they appeared.
8.Application examples
8.1long series of passivated parts
The upper and lower ends of the plating pieces enter and leave the passivated solution successively when the long series of parts are passivated. On the other hand, when the solution is suspended in the air after passivation, the solution flows down from the upper end to the lower end. The surface of the plate at the lower end is more liquid than that at the upper end, and the chemical reaction time between the lower end and the solution is more. All of these make the lower end of the passivating film darker than the upper end. In order to reduce the color difference, it is recommended for such parts to enter and exit the passivated solution horizontally (hook the lower end with a hook) and prevent the anode from being too long.
8.2long strip parts are passivated
Strip parts passivation as passivation tank can hold, can take temporary measures, can use brick or wood processing a hold plating pieces of the box, box lined with plastic sheets, injection can be used after the passivation solution, using this method is convenient and can avoid uneven film layer or create cohesion marks or other product quality problems.
8.3planar parts passivation
Common plane passivation due to swing in the passivation bath edge parts in contact with the passivation solution than the middle part, the colour and lustre of passivation film caused this part uneven phenomenon, this problem is solved to compressed air mixing, the effect is very good. In order to improve the uniformity of the passivation film still need to pay attention to the current distribution uniformity in the process of galvanized, the edge of the plating parts shall be shielded when necessary, to prevent the parts coating roughness by current is too large, affect the colour and lustre of passivation film.
8.4surface passivation
Smooth surface passivated, because the surface is smooth, difficult to adsorption on the surface passivation solution, quickly lost, so the passivation in the solution and the residence time in air should be appropriately extended, otherwise the workpiece passivation membrane appear more light.
8.5easy water pockets passivation
The quality of the passivation film can also be ensured in this part.
8.6passivation of small parts
The whole bundle of the workpieces can be placed in a plastic basket to passivate, so as not to be out of the group due to vibration when passivation, fall into the slot to cause repair.

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